trifluoro(η(5)-n-propyltetramethylcyclopentadienyl)titanium(IV) | 188549-84-0

• 英文名称: trifluoro(η(5)-n-propyltetramethylcyclopentadienyl)titanium(IV)
• CAS: 188549-84-0
• 化学式: C₁₂H₁₉F₃Ti
• 分子量: 268.158
• InChiKey: ZDHUISSCSMVYKI-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  trichloro(η(5)-n-propyltetramethylcyclopentadienyl)titanium(IV) 、 三甲基氟锡烷 以 甲苯 为溶剂， 以84%的产率得到trifluoro(η(5)-n-propyltetramethylcyclopentadienyl)titanium(IV)
  参考文献：
  名称：

  Synthesis and characterisation of trifluoro(η5-n-propyltetramethylcyclopentadienyl) metal(IV)-compounds of the elements of group IV

  摘要：

  A series of trifluoro metal complexes of titanium, zirconium and hafnium containing the n-propyltetramethylcyclopentadienyl ligand (C(5)Me(4)nPr) have been synthesised by metathesis reactions of the trichloro analogue using three equivalents of Me3SnF. X-ray analysis of (C(5)Me(4)nPr)TiF3 1 confirms the presence of two (C(5)Me(4)nPr)TiF3 moieties with two fluorine atoms bridging the metal atoms resulting in a centre of symmetry. The starting materials (C(5)Me(4)nPr)MCl3 (M=Zr, Hf) were prepared by reaction of (C(5)Me(4)nPr)Li with MCl4 (M=Zr, Hf). (C) 1997 Published by Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(96)06669-7