HC.tplbond.CC(Me)(OH)-(η(6)-C6H5)Cr(CO)3 | 192123-29-8

• 英文名称: HC.tplbond.CC(Me)(OH)-(η(6)-C6H5)Cr(CO)3
• CAS: 192123-29-8
• 化学式: C₁₃H₁₀CrO₄
• 分子量: 282.216
• InChiKey: PJHZINQBBHYXJE-CZEDPBFNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  sodium hexaflorophosphate 、 (η(6)-hexamethylbenzene)dichloro(PMe3)ruthenium(II) 、 HC.tplbond.CC(Me)(OH)-(η(6)-C6H5)Cr(CO)3 以 甲醇 为溶剂， 以78%的产率得到[(η(6)-C6Me6)Cl(PMe3)Ru(=C(OMe)CH=C(Me)(η(6)-C6H5))Cr(CO)3]PF6
  参考文献：
  名称：

  Bimetallic Cr, Ru alkenyl carbene derivatives: Synthesis from organometallic prop-2-yn-1-ols and stereochemical aspects

  摘要：

  The reaction of RuCl2(PMe3)(eta 6-C6Me6) 1 with HC=C-CHOH-(2-MeO-C6H4) 2 and NaPF6 in methanol led to the trans-alkenylcarbene complex [LnRu=C(OMe)CH=CH(2-MeO-C6H4)]PF6 3 (LnRu = Ru(Cl)(PMe3)(eta(6)-C6Me6)) with the s-cis conformation of the carbene ligand. The activation by 1 of the racemic and of the (S,S) stereoisomer of the organometallic alcohol HC=CCOH(eta(6)-(2Me-C6H4)Cr(CO)(3) 4 afforded the same two diastereoisomers [LnRu=C(OMe)CH=CH(eta(6)-(2-Me-C6H4)Cr(CO)(3)]PF6 5a/b with low stereoselectivity in the ratio 55:45 (80%) and in the s-cis conformation. By contrast, the activation of HC=CCOH(Me)(eta(6)-C6H5)Cr(CO)(3) 8 by 1 led to two diastereoisomers [LnRu=C(OMe)CH=CMe(eta(6)-C6H5)Cr(CO)(3)]PF6 9a/b (64:34) with the s-trans conformation of the organometallic carbene ligand.

  DOI：

  10.1016/s0022-328x(96)06845-3