| 207859-25-4

• CAS: 207859-25-4
• 化学式: C₂₀H₃₄ClCuN₃O₂
• 分子量: 447.508
• InChiKey: DWDIHHQOWQRKIQ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  sodium;2-tert-butyl-5-[(4,7-dimethyl-1,4,7-triazonan-1-yl)methyl]-4-methoxyphenolate 、 copper dichloride 以 四氢呋喃 、 正戊烷 为溶剂， 以47%的产率得到
  参考文献：
  名称：

  Why Does the Active Form of Galactose Oxidase Possess a Diamagnetic Ground State?

  摘要：

  The relative orientation of the two magnetic orbitals, the CuII d x 2-y 2 orbital and the half-occupied π orbital of the tyrosyl radical, is the key to answering the question in the title. The arrangement shown (CuII -O-C bond angle of about 130° and a dihedral angle of about 90° between the x,y plane of the CuII polyhedron and the tyrosyl ring plane) leads to an overlap of the orbitals, which results in a singlet ground state.

  DOI：

  10.1002/(sici)1521-3773(19980316)37:5<616::aid-anie616>3.0.co;2-4