[Sm2(4-pentyl-4'-cyanobiphenyl)2] | 345201-57-2

• 英文名称: [Sm2(4-pentyl-4'-cyanobiphenyl)2]
• CAS: 345201-57-2
• 化学式: C₃₆H₃₈N₂Sm₂
• 分子量: 799.431
• InChiKey: MSYBQHIQRVUGCT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三氢化钐 、 4'-正戊基-4-氰基联苯 以 neat (no solvent) 为溶剂， 生成 [Sm2(4-pentyl-4'-cyanobiphenyl)2]
  参考文献：
  名称：

  Spectroscopic study of low temperature interactions in Sm-mesogenic cyanophenyl co-condensates

  摘要：

  The IR- and W-Vis spectroscopic study of samarium-mesogenic 4-pentyl-4'-cyanobiphenyl low temperatures co-condensates was made in temperature range 90-300 K. Two labile complexes with different metal/ligand ratio of 1:2 and 1:1 were found. They were characterized by methods of IR- and UV-spectroscopy. The solid state transformation of complex Sm(5CB)(2) to Sm(5CB) was shown to take place at 170-210 K. The kinetics of the process revealed a wide distribution of complex reactivity and of reaction activation energy. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(00)00363-2