mer-[(CH3CH2CH2N(CH2CH2PPh2)2)RuCl(C=C(H)Ph)(C(N(H)Ph)(CH2Ph))]PF6 | 206365-12-0

• 英文名称: mer-[(CH3CH2CH2N(CH2CH2PPh2)2)RuCl(C=C(H)Ph)(C(N(H)Ph)(CH2Ph))]PF6
• CAS: 206365-12-0
• 化学式: C₅₃H₅₄ClN₂P₂Ru*F₆P
• 分子量: 1062.46
• InChiKey: LZZRJUNQZWZFNE-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  mer-[(CH3CH2CH2N(CH2CH2PPh2)2)RuCl(C=C(H)Ph)(C(N(H)Ph)(CH2Ph))]PF6 在 叔丁胺 作用下， 以 四氢呋喃 为溶剂， 以80%的产率得到[(CH3CH2CH2N(CH2CH2PPh2)2)RuCl(C.tplbond.CPh)(C(N(H)Ph)(CH2Ph))]
  参考文献：
  名称：

  Concomitant coordination of vinylidene and carbene ligands made possible at ruthenium(II)

  摘要：

  Removal of one chloride ligand from the aminocarbene fac-[(PNP)RuCl2(C{N(H)Ph}{CH2Ph})] in THF followed by treatment with phenylacetylene yields the ruthenium(II) complex mer-[(PNP)RuCl{C=C(H)Ph}(C{N(H)Ph}{CH2Ph})]PF6 (4). Complex 4 represents the first example of a transition metal complex with the simultaneous coordination of vinylidene and carbene ligands. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(97)05877-5
• 作为产物：
  描述：

  thallium(I) hexafluorophosphate 、 fac,cis-[(CH₃CH₂CH₂N(CH₂CH₂PPh₂)2)RuCl₂(=C(NHPh)CH₂Ph)] 、 苯乙炔 在 四氢呋喃 作用下， 以 四氢呋喃 为溶剂， 以85%的产率得到mer-[(CH3CH2CH2N(CH2CH2PPh2)2)RuCl(C=C(H)Ph)(C(N(H)Ph)(CH2Ph))]PF6
  参考文献：
  名称：

  Concomitant coordination of vinylidene and carbene ligands made possible at ruthenium(II)

  摘要：

  Removal of one chloride ligand from the aminocarbene fac-[(PNP)RuCl2(C{N(H)Ph}{CH2Ph})] in THF followed by treatment with phenylacetylene yields the ruthenium(II) complex mer-[(PNP)RuCl{C=C(H)Ph}(C{N(H)Ph}{CH2Ph})]PF6 (4). Complex 4 represents the first example of a transition metal complex with the simultaneous coordination of vinylidene and carbene ligands. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(97)05877-5