e(S-t-Bu)a(H)-(μ-S-t-Bu)[μ-t-Bu(Me3SiO)CHPH]Fe2(CO)6 | 233676-81-8

• 英文名称: e(S-t-Bu)a(H)-(μ-S-t-Bu)[μ-t-Bu(Me3SiO)CHPH]Fe2(CO)6
• CAS: 233676-81-8；233752-93-7
• 化学式: C₁₈H₂₉Fe₂O₇PSSi
• 分子量: 560.243
• InChiKey: HRSWZIBOJWJFBK-ZMGLHKNASA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  十二羰基三铁 、 (2,2-dimethyl-1-(trimethylsiloxy)propylidene)-trimethylsilylphosphine 、 叔丁基硫醇 在 Et₃N 作用下， 以 苯 为溶剂， 以34%的产率得到e(S-t-Bu)e(H)-(μ-S-t-Bu)[μ-t-Bu(Me3SiO)CHPH]Fe2(CO)6
  参考文献：
  名称：

  Novel Reaction of Complex Salts [(μ-RE)(μ-CO)Fe₂(CO)₆][HNEt₃] (E = S, Se) with Phosphaalkene t-Bu(Me₃SiO)CPSiMe₃. Synthesis and Spectroscopic and Crystallographic Characterization of Butterfly Fe₂EP Clusters (μ-RE)[μ-t-Bu(Me₃SiO)CHPH]Fe₂(CO)₆ (E = S, Se)

  摘要：

  Reaction of complex salts [(mu-RE)(mu-CO)Fe-2(CO)(6)][HNEt3] (1, E = S, Se) with phosphaalkene t-Bu(Me3SiO)C=PSiMe3 (2) has been found to afford a series of new butterfly-shaped Fe2EP clusters of type [(mu-RE)[mu-t-Bu(Me3SiO)CHPH]Fe-2(CO)(6) (3, RE = EtS; 4, n-PrS; 5, n-BuS; 6, t-BuS; 7, PhSe; 8, p-MeC6H4Se) in quite high yields. This type of cluster may exist as three isomers, namely, e(R)e(H), e(R)a(H), and a(R)a(H), which differ in whether the R group and H atom are attached to E and P atoms with an axial pr an equatorial bond. Clusters 3-8 have been characterized by elemental analysis and H-1, P-31, and Se-77 NMR spectroscopy, as well as for isomers 3e(R)a(H), 6e(R)a(H), 8e(R)e(H), and 8a(R)a(H) by single-crystal X-ray diffraction analyses. In addition, a possible reaction mechanism has been preliminarily suggested.

  DOI：

  10.1021/om990331o