[PtCl(2-(diphenylphosphino)aminotriazole-P)(2-(diphenylphosphino)aminothiazole-P,N)][Cl] | 850609-31-3

• 英文名称: [PtCl(2-(diphenylphosphino)aminotriazole-P)(2-(diphenylphosphino)aminothiazole-P,N)][Cl]
• 英文别名: [PtCl(dppat-P)(dppat-P,N)][Cl]
• CAS: 850609-31-3
• 化学式: C₃₀H₂₆ClN₄P₂PtS₂*Cl
• 分子量: 834.629
• InChiKey: VNAXZVXDNHXLDQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 N-(diphenylphosphino)thiazol-2-amine 以 乙腈 为溶剂， 以80%的产率得到[PtCl(2-(diphenylphosphino)aminotriazole-P)(2-(diphenylphosphino)aminothiazole-P,N)][Cl]
  参考文献：
  名称：

  Investigating the effects of steric hindrance on the coordination of 2-aminothiazoyl based ligands

  摘要：

  The ligands 2-(diphenylphosphino)aminothiazole (dppat) 2-(diphenylphosphino)amino-4-methylthiazole (Medppat) and 2-(diphenylphosphino)amino-4-tert-butylthiazole (Budppat) have been prepared. Reaction of these ligand with MCl2 (COD) gives [MCl(dppat-P,N)(dppat-P)][Cl], [MCl(Medppat-P,N)(Medppat-P)][Cl], and [PtCl2 ('Bu-dppat-P-2], respectively. The increased bulk at the 4-position limits the formation of a P, N system in Budppat. The X-ray structure of [PtCl(Medppat-P,N)(Medppat-P)][Cl] reveals that the monodentate ligand has undergone a tautomerism upon coordination. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.06.045