Br(CH3CN)2(CO)2Mo(η(3)-1-C3H4COOMe) | 195886-62-5

• 英文名称: Br(CH3CN)2(CO)2Mo(η(3)-1-C3H4COOMe)
• CAS: 195886-62-5
• 化学式: C₁₁H₁₃BrMoN₂O₄
• 分子量: 413.079
• InChiKey: AYVXXPQGHGFVGQ-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  Br(CH3CN)2(CO)2Mo(η(3)-1-C3H4COOMe) 、 sodium trispyrazolylborate 在 NH₄Cl 作用下， 以 四氢呋喃 为溶剂， 以74%的产率得到dicarbonyl[hydridotris(1-pyrazolyl)borato][syn-(1-3-η)-1-(methoxycarbonyl)propenyl]molybdenum
  参考文献：
  名称：

  Studies on Lateral Stereocontrol Using the (π-Allyl)molybdenum System

  摘要：

  The preparation and reactions of several new (eta(3)-allyl)molybdenum complexes are described. Functionalization of a carbon-carbon double bond adjacent to the pi-allyl unit proceeds stereoselectively, and the stereochemical outcome of this reaction is discussed in light of the Curtin-Hammett principle. It is shown that carbonyl groups can also be functionalized with moderate stereoselectivity, and this behavior is rationalized on the basis of conformational analysis using molecular mechanics calculations.

  DOI：

  10.1021/om970466z