azido-2κN-bis[μ-(1η5:2κP)-diphenylphosphinocyclopentadienyl][2(η5)-pentamethylcyclopentadienyl]iron(III)rhodium(III) hexafluorophosphate | 716337-27-8

• 英文名称: azido-2κN-bis[μ-(1η5:2κP)-diphenylphosphinocyclopentadienyl][2(η5)-pentamethylcyclopentadienyl]iron(III)rhodium(III) hexafluorophosphate
• 英文别名: azido[1,1'-bis(diphenylphosphino)ferrocene](pentamethylcyclopentadienyl)rhodium(III) hexafluorophosphate
• CAS: 716337-27-8
• 化学式: C₄₄H₄₃FeN₃P₂Rh*F₆P
• 分子量: 979.51
• InChiKey: RZMZAKKWBVTLFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  chloro(1,1'-bis(diphenylphosphino)ferrocene)(pentamethylcyclopentadienyl)rhodium(III) hexafluorophosphate 、 叠氮基三甲基硅烷 、 silver nitrate 以 二氯甲烷 、 丙酮 为溶剂， 以62.6%的产率得到azido-2κN-bis[μ-(1η5:2κP)-diphenylphosphinocyclopentadienyl][2(η5)-pentamethylcyclopentadienyl]iron(III)rhodium(III) hexafluorophosphate
  参考文献：
  名称：

  Azido[1,1′-bis(diphenylphosphino)ferrocene](pentamethylcyclopentadienyl)rhodium(III) hexafluorophosphate

  摘要：

  In the title compound, azido-2kappaN-bis[mu-(1eta(5): 2kappaP)-diphenylphosphinocyclopentadienyl][ 2(eta(5))-pentamethylcyclopentadienyl] iron(III) rhodium(III) hexafluorophosphate, [{Rh(C10H15)( N-3)}{Fe(mu-C17H14P)(2)}] PF6 or [FeRh(C10H15)(mu-C17H14P)(2)(N-3)] PF6, the coordination sphere of Rh-III can be described as pseudo-tetrahedral, composed of two P atoms from a 1,1'-bis( diphenylphosphino) ferrocene (dppf) ligand, an azido N atom and the centroid of the ring of a C5Me5 (Cp*) ligand. The two cyclopentadienyl rings in the dppf moiety adopt an eclipsed conformation. The Rh...Fe distance is 4.340 (2) Angstrom.

  DOI：

  10.1107/s0108270104004779