[2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]-2-pentane](methyl)(trifluoromethanesulfonate)gallium(III) | 1312446-12-0

• 英文名称: [2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]-2-pentane](methyl)(trifluoromethanesulfonate)gallium(III)
• CAS: 1312446-12-0
• 化学式: C₃₁H₄₄F₃GaN₂O₃S
• 分子量: 651.486
• InChiKey: HNQZJNYPIQXKGG-IEBALEEYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (1,5-cyclooctadiene)PdMe(OTf) 、 [2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]-2-pentane]gallium(I) 以 氟苯 、 甲苯 为溶剂， 以33%的产率得到[2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]-2-pentane](methyl)(trifluoromethanesulfonate)gallium(III)
  参考文献：
  名称：

  Synthesis and structure of new compounds with Pt–Ga bonds: Insertion of the bulky gallium (I) bisimidinate Ga(DDP) into Pt–Cl bond

  摘要：

  Reactions of the sterically bulky mono-valent group 13 bisimidinate gallium(I), Ga(DDP) (1) (DDP = 2-{(2, 6-diisopropylphenyl) amino}-4-{(2, 6-diisopropylphenyl) imino}-2-pentene, HC (CMeNC6H3-2,6-Pr-i(2)) 2) with olefin supported group 10 complexes, [(diene)PtCl2] [diene = 1,5-cyclooctadiene (COD), endo-dicyclopentadiene (dcy)] and [(COD)Pd(Me)(OTf)] (OTf = O3SCF3) are reported. These reactions afforded [(COD)Pt(Cl){ClGa(DDP)}] (2), [(dcy) Pt(Cl){ClGa(DDP)}] (3) and [(DDP)Ga(Me)(OTf)] (4) in moderate yields. Compounds 2-4 were characterized by elemental analysis, NMR (H-1, C-13) spectroscopy and also by single crystal X-ray structural analysis. The solid state structures of complexes 2 and 3 reveal the oxidative insertion of Ga(DDP) into the PteCl bond without altering the p-coordinated double bonds in the olefin. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.04.008