| 181589-88-8

• CAS: 181589-88-8
• 化学式: C₄₀H₅₀P₂Zr
• 分子量: 684.009
• InChiKey: XMSJCPXFYVRGHR-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  、 二苯基膦 以 苯 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Zr−E π-Bonding in Complexes Derived from E−H Additions to Cp₂Zr(P(C₆H₂-2,4,6-t-Bu₃))(PMe₃)

  摘要：

  Additions of PhEH (E = O, S), PhEH(2) (E = N, P), MesPH(2), and Ph(2)PH to Cp(2)Zr(PR*)-(PMe(3)) (2) provide a facile route to complexes of the form Cp(2)Zr(PHR*)(ER) (R* = 2,4,6-t-Bu-C6H2; ER = OPh (3), SPh (4), NHPh (5), PHPh (6), PHMes (7), PPh(2) (8)). Variable-temperature NMR studies are consistent with facile metal-mediated inversion at phosphorus as well as rapid rotation about the Zr-E bonds at room temperature.

  DOI：

  10.1021/om960314o