[Zn2(κ3-2,3,5,6-tetra(2-pyridyl)pyrazine)Cl4]*H2O | 1106709-21-0

• 英文名称: [Zn2(κ3-2,3,5,6-tetra(2-pyridyl)pyrazine)Cl4]*H2O
• CAS: 1106709-21-0
• 化学式: C₂₄H₁₆Cl₄N₆Zn₂*H₂O
• 分子量: 679.039
• InChiKey: HDISPFATAYGCHA-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  zinc chloride 、 四-2-吡啶基吡嗪 以 乙腈 为溶剂， 以81%的产率得到[Zn2(κ3-2,3,5,6-tetra(2-pyridyl)pyrazine)Cl4]*H2O
  参考文献：
  名称：

  Binuclear copper and zinc complexes based on polypyridyl ligand 2,3,5,6-tetra(2-pyridyl)pyrazine (tppz): Synthesis, spectral and structural characterization

  摘要：

  The reaction of MCl2 center dot 2H(2)O (M = Cu, Zn) with 2,3,5,6-tetra(2-pyridyl)pyrazine (tppz) (referred hereafter as L) in 2:1 molar ratio in acetonitrile at room temperature afforded binuclear complexes [M-2(k(3)-L)Cl-4] [Cu (1), Zn (2)] where the ligand is bis-tridentate manner. The complexes have been characterized by elemental analyses, FAB-MS, IR, EPR, NMR and electronic spectral studies. Solid state structures of both the [Cu-2(k(3)-L)Cl-4] center dot 5H(2)O (1), [Zn-2(k(3)-L)Cl-4] center dot H2O (2) have been determined by single crystal X-ray analyses. A well-resolved uudd cyclic water tetramer and water monomer were reported in the crystal host of [Cu-2(k(3)-L)Cl-4] center dot 5H(2)O (1) and [Zn-2(k(3)-L)Cl-4] center dot H2O (2) showing the contribution of the water cluster to the stability of the crystal host 1 and 2. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.02.064