[Cr4(CH2CH2CH2NMe2)4(μ4-O)(μ-Cl)6] | 228859-98-1

• 英文名称: [Cr4(CH2CH2CH2NMe2)4(μ4-O)(μ-Cl)6]
• CAS: 228859-98-1
• 化学式: C₂₀H₄₈Cl₆Cr₄N₄O
• 分子量: 781.329
• InChiKey: QKBHHKGUTVIYNE-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  trichlorotris(tetrahydrofuran)chromium(III) 、 3-dimethylaminopropyllithium 以 四氢呋喃 为溶剂， 以24%的产率得到[Cr4(CH2CH2CH2NMe2)4(μ4-O)(μ-Cl)6]
  参考文献：
  名称：

  Synthesis and molecular structure of the tetranuclear μ4-oxo-centered chromium complex [Cr4(CH2CH2CH2NMe2)4(μ4-O)(μ-Cl)6]

  摘要：

  The complex [CrCl3(THF)(3)] reacts with Li(CH2CH2CH2NMe2) in THF at room temperature (r.t.) to form the tetranuclear complex [Cr-4(CH2CH2CH2NMe2)(4)(mu(4)-O)(mu-Cl)(6)] (1) where each chromium atom has a distorted octahedral coordination geometry with an oxygen atom shared among the four metal ions. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)01091-2