2-(2'-diphenylphosphanylnaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II) | 942608-43-7

• 英文名称: 2-(2'-diphenylphosphanylnaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II)
• CAS: 942608-43-7
• 化学式: C₄₄H₄₂P₂Ru
• 分子量: 733.835
• InChiKey: BKHJTKHGOBRVPI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 二氯甲烷 、 2-(2'-diphenylphosphanylnaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II) 以 氯仿 为溶剂， 以64%的产率得到cis-[2-(2'-diphenylphosphanyl-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)Ru]PtCl2*2CH2Cl2
  参考文献：
  名称：

  Planar-to-Axial Chirality Relay in Phospharuthenocenes. A Rotationally Hindered 2-(2‘-Diphenylphosphinonaphth-1‘-yl)phospharuthenocene

  摘要：

  Competing steric pressures within the coordination sphere of 2-(2'-X-naphth-1'-yl)-3,4-dimethyl-5-phenyl-eta(5)-phospholyl(pentamethylcyclopentadienyl)ruthenium(II) complexes (X = OMe (1), OH (3), OTf (4), PPh2(O) (5), PPh2 (6)) give rise to a well-defined and predictable axial chirality about the phospharuthenocene-naphthyl bond. Crystal structure analysis of the platinum complex cis-[Pt(6)Cl-2] (7) shows a very different geometry from that found in cis-[Pt(1)(PEt3)Cl-2] (2) because of the leverage exerted on the Pt coordination sphere by the (2'-PPh2-naphth-1'-yl) functionality.

  DOI：

  10.1021/om0610905
• 作为产物：
  描述：

  2-(2'-P(O)Ph2-naphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II) 、 Diphenylphosphine oxide 在 poly(methylhydrosiloxane) 、 titanium tetra(isopropoxide) 、 sodium hydrogen carbonate 作用下， 以 四氢呋喃 为溶剂， 以93%的产率得到2-(2'-diphenylphosphanylnaphth-1'-yl)-3,4-dimethyl-5-phenyl-η5-phospholyl(pentamethylcyclopentadienyl)ruthenium(II)
  参考文献：
  名称：

  Planar-to-Axial Chirality Relay in Phospharuthenocenes. A Rotationally Hindered 2-(2‘-Diphenylphosphinonaphth-1‘-yl)phospharuthenocene

  摘要：

  Competing steric pressures within the coordination sphere of 2-(2'-X-naphth-1'-yl)-3,4-dimethyl-5-phenyl-eta(5)-phospholyl(pentamethylcyclopentadienyl)ruthenium(II) complexes (X = OMe (1), OH (3), OTf (4), PPh2(O) (5), PPh2 (6)) give rise to a well-defined and predictable axial chirality about the phospharuthenocene-naphthyl bond. Crystal structure analysis of the platinum complex cis-[Pt(6)Cl-2] (7) shows a very different geometry from that found in cis-[Pt(1)(PEt3)Cl-2] (2) because of the leverage exerted on the Pt coordination sphere by the (2'-PPh2-naphth-1'-yl) functionality.

  DOI：

  10.1021/om0610905