| 54375-27-8

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属有机体
• CAS: 54375-27-8
• 化学式: CHO₂
• 分子量: 45.0177
• InChiKey: GGGKZAJVJDLZQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  2
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 大鼠1,25-二羟基维生素D(1,25(OH)2D)试剂盒
  参考文献：
  名称：

  Development of the flowing afterglow/Langmuir probe technique for studying the neutral products of dissociative recombination using spectroscopic techniques: OH production in the HCO⁺₂+ereaction

  摘要：

  The flowing afterglow/Langmuir probe (FALP) technique has been extended to enable the neutral products of electron–ion dissociative recombination in thermalized afterglows to be identified by spectroscopic methods. Absolute number densities of H atoms in the afterglow have been determined using vacuum ultraviolet (VUV) absorption at the Lα wavelength. By exploiting the reaction H+NO2→OH+NO, all of the H atoms can be incorporated into OH molecules and thus observation of the intensity of laser induced fluorescence (LIF) If, obtained by exciting the (1,0) band of OH(A 2Σ←X 2Π), allows a calibration to be obtained of If against the known number density of OH X 2Π(ν″=0) in the afterglow. Following this procedure, a recombining HCO+2 /electron afterglow was probed for production of ground state OH X 2Π(ν″=0) using LIF and it was established that OH(ν″=0) resulted from 17% of the recombining ground state HCO+2 ions. It was also established that a further 17% of the recombinations resulted in OH(ν″>0), i.e., that, in total, (34±6)% of the HCO+2 ions recombine to produce OH X 2Π radicals, either directly or via the electronically excited A 2Σ state. Details of the calibration procedure for H and OH number densities, of the ion chemistry involved in the production of the HCO+2 afterglow plasmas and of the checks carried out to establish that the fluorescence observed was from OH produced in the recombination reaction are presented. During these experiments, the rate coefficient at 300 K for the H+NO2 reaction was determined to be 1.3×10−10 cm3  s−1 from observations of the H-atom decay as a function of NO2 number density in the afterglow (in good agreement with previous determinations). Also the rate coefficient for the quenching reaction of OH(ν″>0) with NO to produce OH(ν″=0) was determined to be 6×10−11 cm3  s−1.

  DOI：

  10.1063/1.457148

文献信息

• Gas Phase Reactions of Some Positive Ions with Atomic and Molecular Oxygen and Nitric Oxide at 300 K
  作者：Graham B. I. Scott、David A. Fairley、Daniel B. Milligan、Colin G. Freeman、Murray J. McEwan

  DOI：10.1021/jp9913719

  日期：1999.9.1

  Rate coefficients and product ion distributions have been determined for the reactions of HCNH+, HC3N+, H2C3N+, H2O+, N-2(+), HCO+, and HCO2+ with O atoms in a selected ion flow tube at 295 +/- 5 K. Only two of these ions, HC3N+ and N-2(+), were found to react with atomic oxygen, and both ions exhibited multiple reaction channels. Reactions with O atoms may be relevant to synthetic processes occurring in some interstellar clouds. Because of the application of the N + NO titration to determine O atom concentrations, the rate coefficient and product distribution for the reaction of each ion with O-2 and NO was also measured.