| 1581741-62-9

• CAS: 1581741-62-9
• 化学式: C₉₀H₇₅InN₆
• 分子量: 1355.45
• InChiKey: NLURQYLGYNPWKY-KGRFRKIYSA-N

反应信息

• 作为产物：
  描述：

  indium(III) chloride 、 、 2-(Mesityl(2H-pyrrol-2-ylidene)methyl)-1H-pyrrole 在 lithium hexamethyldisilazane 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以36%的产率得到
  参考文献：
  名称：

  Luminescent Heteroleptic Tris(dipyrrinato)indium(III) Complexes

  摘要：

  To provide an improvement over the low fluorescence efficiencies often shown by homoleptic tris(dipyrrinato)indium(III) complexes, luminescent heteroleptic tris(dipyrrinato)indium(III) complexes bearing two types of dipyrrinato ligands are designed here by theoretical calculation and then synthesized. They possess frontier orbitals linked to suppression of the nonemissive charge-separated states; one shows a high fluorescence quantum yield (0.41) in toluene, which exceeds that of the corresponding BF2 complex.

  DOI：

  10.1021/ic500326u