| 182863-23-6

• CAS: 182863-23-6
• 化学式: C₄₅H₃₉AuClMoO₄P₃
• 分子量: 1065.08
• InChiKey: BAHRRVGSJOZNBZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 thallium(I) 2,4-pentanedionate 以 二氯甲烷 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  Synthesis of heteropolynuclear complexes with 1,1,1-tris(diphenylphosphinomethyl)ethane. Crystal structure of [(OC)₄Mo{(Ph₂PCH₂)₂CMe(CH₂PPh₂)}AuCl]

  摘要：

  Treatment of [M(CO)(4){(Ph(2)PCH(2))(2)CMe(CH(2)PPh(2))}] (M = Mo or W) with neutral or cationic gold-(I) or -(III) derivatives afforded bi- or tri-nuclear complexes containing the triphosphine (Ph(2)PCH(2))(3)CMe (tdppme) acting as a mu-P,P',P '' ligand, a co-ordination mode poorly represented thus far. The binuclear derivative [(OC)(4)Mo(tdppme)AuCl] further reacts with 1 equivalent of Tl(acac) (acac = acetylacetonate) to afford [(OC)(4)Mo(tdppme)Au(acac)]. This complex acts as a deprotonating agent in reactions with various starting materials containing phosphines such as (Ph(2)P)(2)CH2 or (Ph(2)P)(3)CH, leading to the formation of trinuclear methanide complexes. The crystal structure of [(OC)(4)Mo(tdppme)AuCl] has been established by X-ray crystallography.

  DOI：

  10.1039/dt9960003603
• 作为产物：
  描述：

  1,1,1-三(二苯基膦甲基)乙烷 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of heteropolynuclear complexes with 1,1,1-tris(diphenylphosphinomethyl)ethane. Crystal structure of [(OC)₄Mo{(Ph₂PCH₂)₂CMe(CH₂PPh₂)}AuCl]

  摘要：

  Treatment of [M(CO)(4){(Ph(2)PCH(2))(2)CMe(CH(2)PPh(2))}] (M = Mo or W) with neutral or cationic gold-(I) or -(III) derivatives afforded bi- or tri-nuclear complexes containing the triphosphine (Ph(2)PCH(2))(3)CMe (tdppme) acting as a mu-P,P',P '' ligand, a co-ordination mode poorly represented thus far. The binuclear derivative [(OC)(4)Mo(tdppme)AuCl] further reacts with 1 equivalent of Tl(acac) (acac = acetylacetonate) to afford [(OC)(4)Mo(tdppme)Au(acac)]. This complex acts as a deprotonating agent in reactions with various starting materials containing phosphines such as (Ph(2)P)(2)CH2 or (Ph(2)P)(3)CH, leading to the formation of trinuclear methanide complexes. The crystal structure of [(OC)(4)Mo(tdppme)AuCl] has been established by X-ray crystallography.

  DOI：

  10.1039/dt9960003603