[Zn(5-ferrocene-1,3-benzenedicarboxylate)(1,10-phenathroline)(H2O)]*MeOH | 1075734-56-3

• 英文名称: [Zn(5-ferrocene-1,3-benzenedicarboxylate)(1,10-phenathroline)(H2O)]*MeOH
• CAS: 1075734-56-3
• 化学式: CH₄O*C₁₂H₈N₂*C₁₈H₁₂FeO₄*H₂O*Zn
• 分子量: 643.794
• InChiKey: GBKHBHQAJJXIHD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 1,10-菲罗啉 、 zinc(II) nitrate hexahydrate 、 5-ferrocene-1,3-benzenedicarboxylic acid 在 Et₃N 作用下， 以 甲醇 为溶剂， 以42%的产率得到[Zn(5-ferrocene-1,3-benzenedicarboxylate)(1,10-phenathroline)(H2O)]*MeOH
  参考文献：
  名称：

  Novel coordination polymers with ferrocene-containing dicarboxylate ligand: Syntheses, crystal structures and properties

  摘要：

  A new ferrocene-containing dicarboxylate ligand, L=5-ferrocene-1,3-benzenedicarboxylic acid, has been prepared. Self-assembly of L, M(II) salts (M=Co and Zn) and chelating ligands dpa or phen (dpa=2,2'-dipyridylamine and phen=1,10-phen) gave rise to four new coordination polymers {[Co(L) (dpa)] center dot 2MeOH}(n) (1), {[Zn(L)(dpa)] center dot 2MeOH}(n) (2), {[Co(L)(phen)(H2O)] center dot MeOH} (3), [Zn(L)(phen) (H2O)] center dot MeOH (4). The isostructural complexes 1 and 2 possess 1D helical chain structures with 2(1) screw axes along the b-direction, and the right-and left-handed helical chains are alternate arrayed into 2D layer structures through hydrogen-bonding interactions; while isostructural complexes 3 and 4 are 1D linear chain structures with phen and ferrocene groups of L as pendants hanging on the different sides of the main chain. A structural comparison of complexes 1-4 demonstrated that the characteristics of subsidiary ligands and slight difference in coordination models of L play very important role in the construction of the complexes. In addition, the redox properties of complexes 1-4, as well as the magnetic properties of complexes 1 and 3 are also investigated. (C) 2008 Published by Elsevier B. V.

  DOI：

  10.1016/j.jorganchem.2008.07.034