[(η-2-ClC6H4NHCH2COOH)(η-C5H5)Fe][PF6] | 197140-05-9

• 英文名称: [(η-2-ClC6H4NHCH2COOH)(η-C5H5)Fe][PF6]
• CAS: 197140-05-9
• 化学式: C₁₃H₁₃ClFeNO₂*F₆P
• 分子量: 451.516
• InChiKey: ZIULPRPMPCZBSK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (η6-1,2-dichlorobenzene)(η5-cyclopentadienyl)iron(II) hexafluorophosphate 、 甘氨酸甲酯盐酸盐 在 sodium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以27%的产率得到[(η-2-ClC6H4NHCH2COOH)(η-C5H5)Fe][PF6]
  参考文献：
  名称：

  Synthesis, stereochemistry and decomplexation of (η-arene)(η-cyclopentadienyl) iron(II) hexafluorophosphate complexes containing amino acid side chains. A route to N-arylamino acids

  摘要：

  [(eta-Substituted arene)(eta-cyclopentadienyl)Fe][PF6] complexes with amino acid side chains on the arene ring have been prepared by reaction of [(eta-haloarene)(eta-cyclopentadienyl)Fe][PF6] complexes with amino acids and amino acid eaters under various conditions. Evidence is presented from H-1-and C-13-NMR spectroscopy for the existence of conformational isomers resulting from restricted rotation about the arene-nitrogen bond. Where a chlorine substituent is also present in the complexed arene, diastereoisomers can be separated by column chromatography. Decomplexation of the complexes is reported in strongly basic media or using 1,8-phenanthroline in light-catalysed reactions offering a new route to N-arylamino acids. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00292-1