Complex Chemical Stabilization of Dichlorodiphosphene
摘要:
In contrast to the cis configuration of N2 F2 , the analogous phosphorus subhalogenides, P2 X2 (X=F, Cl) adopt a trans configuration according to density functional theory calculations. Now for the first time dichlorodiphosphene has been stabilized in the coordination sphere of transition metals in the form of complex 1.