tetracarbonyl(η5-pentachlorocyclopentadienyl)vanadium | 115420-99-0

• 英文名称: tetracarbonyl(η5-pentachlorocyclopentadienyl)vanadium
• CAS: 115420-99-0
• 化学式: C₉Cl₅O₄V
• 分子量: 400.303
• InChiKey: WRSJGVZRZZFCCV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  tetracarbonyl(η5-pentachlorocyclopentadienyl)vanadium 在 氮 作用下， 以 gaseous matrix 为溶剂， 生成 (η5-C5Cl5)V(CO)3(N2) 、 (η3-C5Cl5)V(CO)4(N2)
  参考文献：
  名称：

  在低温基质中，环取代的半夹心四羰基钒配合物在低温下的比较光化学。12 K

  摘要：

  Infrared spectroscopic evidence is presented showing that photolysis of a variety of ring-substituted half-sandwich tetracarbonylvanadium complexes (ring: eta5-C5Me5, eta5-C5H4Me, eta5-indenyl, eta5-C5Cl5) in Ar and CH4 matrices at high dilution at ca. 12 K affords reversible CO ejection and partial ring dechelation. For the eta5-C5H4Me and eta5-C5Cl5, compounds, further photolysis led to dicarbonyl species. In N2 MatriCes reversible ring dechelation was aw observed but the CO loss species reacted with N2 to yield mono- and bis(dinitrogen) species. In CO matrices reversible ring dechelation was still observed but there was no evidence for CO uptake by these species resulting in complete ejection of the cyclopentadienyl rings. In 02 matrices photolysis of (eta5-C5Me5)V(CO)4 led to the formation of (eta5-C5Me5)V(CO)3(02) with a side-on bonded 02 ligand, ag confirmed using an O-18(2) matrix. In Ar matrices doped with H2S and tetrahydrofuran (THF), there was no evidence for uptake of the donor ligands. In poly(vinyl chloride) films photolysis Of (eta5-C5Me5)V(CO)4 also gave both the CO loss and the ring dechelation product at 12 K, but as the film was warmed, bands were observed which were consistent with the formation Of (eta5-C5Me5)V(CO)3(THF). The photoreactions at 12 K are discussed and compared to those of (eta5-C5H5)V(CO)4 and related to the preparative and mechanistic thermal and photochemical reactions at ambient temperatures. It is apparent that more credence should be given to ring dechelation/ring slippage pathways when reaction mechanisms are discussed.

  DOI：

  10.1021/om00059a030
• 作为产物：
  描述：

  六羰基钒 、 六氯环戊二烯 以 正己烷 为溶剂， 以45%的产率得到tetracarbonyl(η5-pentachlorocyclopentadienyl)vanadium
  参考文献：
  名称：

  Priebsch, Wolfgang; Hoch, Martin; Rehder, Dieter, Chemische Berichte, 1988, vol. 121, p. 1971 - 1976

  摘要：

  DOI：