| 403823-36-9

• CAS: 403823-36-9
• 化学式: C₁₄H₁₂O₁₀P₂S₂W₂
• 分子量: 834.023
• InChiKey: ALTAZDAEQIESFB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  六羰基钨 、 四甲基二膦烷二硫化物 以 苯 为溶剂， 以38%的产率得到
  参考文献：
  名称：

  PHOTOCHEMICAL SYNTHESIS OF METAL CARBONYL COMPLEXES OF TETRAALKYLDIPHOSPHINE DISULFIDES, [M₂(CO)₁₀(μ-R₂P(S)P(S)R₂)] (M = Mo, W; R = Me, Et,n-Pr,n-Bu)

  摘要：

  The new complexes [M-2(CO)(10)(mu-R2P(S)P(S)R-2)] (M = Mo, W: R = Me, Et, n-Pr, n-Bu), (1a)-(1d) and (2a)-(2d) [(1a), M = Mo, R = Me, (1b). M = Mo, R = Et; (1c), M = Mo, R = n-Pr, (1d), M = Mo, R = n-Bu. (2a), M = W, R = Me, (2b), M = W, R = Et, (2c), M = W, R n-Pr, (2d). M = W, R = n-Bu] have been prepared by the photochemical reaction of M(CO)(6) with R2P(S)P(S)R-2 (R = Me, Et, n-Pr, n-Bu). The complexes have been characterized by elemental analyses, FT-IR and P-31-[H-1]-NMR spectroscopy and FAB-mass spectrometry. The spectroscopic studies suggest cis-bridging bidentate coordination of the ligand between the two metals.

  DOI：

  10.1081/sim-100108266