(μ3-CS3)2Mn4(CO)16 | 516480-57-2

• 英文名称: (μ3-CS3)2Mn4(CO)16
• CAS: 516480-57-2
• 化学式: C₁₈Mn₄O₁₆S₆
• 分子量: 884.336
• InChiKey: BMEMWLOKKRPPMT-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二硫化碳 、 羰基镁 以 二硫化碳 为溶剂， 以39%的产率得到(μ3-CS3)2Mn4(CO)16
  参考文献：
  名称：

  Reactions of cyclomanganated complexes with carbon disulfide: routes to η2-aryldithiocarboxylate-Mn(CO)4 complexes and to the trithiocarbonate complex (μ3-CS3)2Mn4(CO)16

  摘要：

  Reaction of cyclomanganated aryl ketones with CS2 proceeds with insertion into the Mn-C bond to give eta(2)-dithiocarboxylato-Mn(CO)(4) compounds. With other cyclomanganated substrates such as that from Ph3P=S and also with Mn-2(CO)(10), CS2 gives (mu(3)-CS3)(2)Mn-4(CO)(16) with bridging trithiocarbonate ligands. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)02024-7

文献信息

• Manganese carbonyl-mediated reactions of azabutadienes with phenylacetylene, methyl acrylate and other unsaturated molecules
  作者：Wade J. Mace、Lyndsay Main、Brian K. Nicholson、Daniel J. van de Pas

  DOI：10.1016/j.jorganchem.2004.04.042

  日期：2004.8

  Reaction of PhCH2Mn(CO)(5) with 1,4-di-aryl-1-aza-1,3-butadienes gave substituted pyrrolinonyl rings which Were eta(4)-coordinated to a Mn(CO)(3) group. These are formed by intramolecular CO insertion into a (non-isolated) cyclomanganated intermediate, followed by cyclisation. Other unsaturated reagents (PhC drop CH, CH2 = CHCOOMe, PhNCO) gave products arising from insertion of these, including a structurally characterised tri-aryl-eta(5)-azacyclohexadienyl-Mn(CO)(3) complex from the reaction with the alkyne. (C) 2004 Elsevier B.V. All rights reserved.