| 239444-68-9

• CAS: 239444-68-9
• 化学式: C₃₂H₂₂Cl₂N₄O₄Pd₂
• 分子量: 810.297
• InChiKey: UNQKXHUMDNIBPJ-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  、 thallium(I) 2,4-pentanedionate 以 二氯甲烷 为溶剂， 以87%的产率得到
  参考文献：
  名称：

  Cyclometallated compounds. XIII. Cyclopalladation of 2-phenoxypyridine and structurally-related compounds

  摘要：

  2-Phenoxypyridine and 2-phenylsulfanylpyridine are cyclopalladated readily by palladium acetate to give six-membered metallocycles. Extension to the three isomeric bis(2-pyridyloxy)benzenes leads to a new series of doubly-cyclopalladated compounds. In contrast, 3-6-diphenoxypyridazine and 4-6-diphenoxypyrimidine only undergo monopalladation, whilst their sulfur analogues are resistant to cyclopalladation. All cyclometallated compounds are converted to their acetylacetonate derivatives and the X-ray crystal structure of one of these is described. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)01203-0
• 作为产物：
  描述：

  、 lithium chloride 以 水 、 丙酮 为溶剂， 以63%的产率得到
  参考文献：
  名称：

  Cyclometallated compounds. XIII. Cyclopalladation of 2-phenoxypyridine and structurally-related compounds

  摘要：

  2-Phenoxypyridine and 2-phenylsulfanylpyridine are cyclopalladated readily by palladium acetate to give six-membered metallocycles. Extension to the three isomeric bis(2-pyridyloxy)benzenes leads to a new series of doubly-cyclopalladated compounds. In contrast, 3-6-diphenoxypyridazine and 4-6-diphenoxypyrimidine only undergo monopalladation, whilst their sulfur analogues are resistant to cyclopalladation. All cyclometallated compounds are converted to their acetylacetonate derivatives and the X-ray crystal structure of one of these is described. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)01203-0