| 219789-39-6

• CAS: 219789-39-6
• 化学式: C₂₆H₂₄Mo₂O₄S₂Se₂
• 分子量: 814.406
• InChiKey: ZELIKZXHQFXHIY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  selenium 、 cis-[(η5-C5H4CO2Me)Mo(CO)(μ-SPh)]2 以 甲苯 为溶剂， 以41%的产率得到
  参考文献：
  名称：

  Reaction of Mo  Mo doubly-bonded complexes (η5-RC5H4) 2Mo2 (CO) 2 (μ-SPh) 2 with elemental selenium. Synthesis and structural characterization of some novel sulfur\selenium quadruply-bridged molybdenum complexes

  摘要：

  The reaction of Mo=Mo doubly-bonded (eta(5)-RC5H4)(2)Mo-2(CO)(2)(mu-SPh)(2) (R = MeO2C, EtO2C) with elemental selenium in toluene at reflux results in formation of a series of sulfur/selenium quadruply-bridged complexes trans/anti-(eta(5)-RC5H4)(2)Mo-2(mu-Se)(2)(mu-SPh)(2) (1a, R = MeO2C; 2a, R = EtO2C), trans/syn-(eta(5)-RC5H4)(2)Mo-2(mu-Se)(2)(mu-SPh)(2) (1b, R = MeO2C; 2b, R = EtO2C), and cis/syn-(eta(5)-RC5H4)(2)Mo-2(mu, eta(2):eta(2)- Se-2)(mu-SPh)(2) (1c, R = MeO2C;2c, R = EtO2C) in 58% and 53% overall-yields, respectively. The structures of all these new products have been characterized by elemental analysis, IR,H-1 NMR and MS,spectroscopies, as well as for 2c by X-ray crystallography. (C) 1998 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00178-8