[(tert-butylamido)bis(μ-tert-butylimido)tris(tert-butylimido)dirhenium(VI)] trifluoromethanesulfonate | 181050-81-7

• 英文名称: [(tert-butylamido)bis(μ-tert-butylimido)tris(tert-butylimido)dirhenium(VI)] trifluoromethanesulfonate
• CAS: 181050-81-7
• 化学式: CF₃O₃S*C₂₄H₅₅N₆Re₂
• 分子量: 949.225
• InChiKey: IVNKMKOEQMHCNS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis[μ-tert-butylimidodi-tert-butylimidorhenium(VI)] 、 三氟甲磺酸 以 乙醚 为溶剂， 以51%的产率得到[(tert-butylamido)bis(μ-tert-butylimido)tris(tert-butylimido)dirhenium(VI)] trifluoromethanesulfonate
  参考文献：
  名称：

  Reactions of electrophiles with [Bu^tN)₂Re^VI(µ-NBu^t)]₂

  摘要：

  The interaction of [(Bu(t)N)(2)Re-VI(mu-NBu(t))](2) 1 with trifluoromethanesulfonic acid gave the amido complex [(Bu(t)N)(Bu(t)HN)Re(mu-NBu(t))(2)Re(NBu(t))(2)][CF3SO3], where the cation has a structure very similar to that of its manganese(VI) analogue. The interaction of 1 with silver triflate differs from the similar reaction with [(Bu(t)N)(2)Mn-VI(mu-NBu(t))](2) in that a silver complex {[(Bu(t)N)Re(mu-NBu(t))](2)(mu-NBu(t))(2)Ag(mu-O3SCF3)}(2) that has NBu(t) groups bridging both rhenium and silver atoms with the latter having mu-O3SCF3 bridges is formed. A similar complex [(Bu(t)N)Re(mu-NBu(t))](2)(mu-NBu(t))(2)Cu-2(O3SCF3)(2) was obtained by interaction of 1 with Cu(O-3-SCF3). 0.5C(6)H(6) but this has Re(mu-NBu(t))Cu(O3SCF3) groups. Interaction of 1 with Al(O3SCF3)(3) . nCF(3)SO(3)H in CH2Cl2 gave a linear molecule (Bu(t)N)(2)Re(mu-NBu(t))(2)Re(NBu(t))(mu-OH)(2)Al(O3SCF3)(3)(H2O). The crystal structures of four compounds have been determined. An improved synthesis of 1 involving Na/Hg reduction of Re(NBu(t))(3)I was elaborated.

  DOI：

  10.1039/dt9960002995