4,4-dimethyl-1,3,5,7,8-pentamethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene | 1312752-36-5

• 英文名称: 4,4-dimethyl-1,3,5,7,8-pentamethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene
• CAS: 1312752-36-5
• 化学式: C₂₀H₃₁BN₂
• 分子量: 310.291
• InChiKey: GCENKUCOWZPXSX-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  4,4-dimethyl-1,3,5,7,8-pentamethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene 在 copper(II) nitrate trihydrate 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 反应 0.08h， 以38%的产率得到4,4-dimethyl-3-nitro-1,5,7,8-tetramethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene
  参考文献：
  名称：

  Reactions of BODIPY Fluorophore with Cupric Nitrate

  摘要：

  4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) and corresponding 4,4-dimethyl and 4,4-diphenyl analogues were treated with cupric nitrate trihydrate under different conditions. Corresponding 3-nitro-, nitromethyl-, hydroxymethyl BODIPY, and BODIPY 3-carboxyaldehyde were obtained. The UV/vis and fluorescent properties of these BODIPY analogues were determined.

  DOI：

  10.1055/s-0034-1379108
• 作为产物：
  描述：

  甲基溴化镁 、 硼,[3-乙基-5-[1-(4-乙基-3,5-二甲基-2H-吡咯-2-亚基-kN)乙基]-2,4-二甲基-1H-吡咯酸根-kN]二氟-,(T-4)- 以 二氯甲烷 为溶剂， 生成 4,4-dimethyl-1,3,5,7,8-pentamethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene
  参考文献：
  名称：

  Some observations relating to the stability of the BODIPY fluorophore under acidic and basic conditions

  摘要：

  4,4-Difluoro-4-bora-1,3,5,7-tetramethyl-2,6-diethyl-8-methyl-3a,4a-diaza-s-indacene (BODIPY) fluorophore was transformed into its corresponding 4,4-dimethyl, 4,4-dimethoxy and 4,4-diphenyl analogues. The stabilities of these BODIPY fluorophores in acidic (di- and trichloroacetic acid) and basic conditions (aqueous ammonium hydroxide) were investigated using B-11 NMR spectroscopy. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.03.027