| 180294-74-0

• CAS: 180294-74-0；318294-02-9
• 化学式: C₂₈H₂₂N₄O₈Ru₂
• 分子量: 744.645
• InChiKey: VHDHJGPYJHYPTQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cis(CO)-[Ru(II)(2,2'-bipyridine)(CO)2(C(O)OMe)Cl] 以 乙腈 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Selective Synthesis and Electrochemical Behavior of trans(Cl)- and cis(Cl)-[Ru(bpy)(CO)₂Cl₂] Complexes (bpy = 2,2‘-Bipyridine). Comparative Studies of Their Electrocatalytic Activity toward the Reduction of Carbon Dioxide

  摘要：

  A synthetic procedure for the selective preparation (ca. 75% isolated yield) of trans(Cl)- and cis(Cl)-[Ru(bpy)(CO)(2)Cl-2] complexes 1 and 2, using an oligomeric [Ru(CO)(2)Cl-2](n) precursor, is described. The synthetic methodology also gives access to the cis(CO)-[Ru(bpy)(CO)(2)(C(O)OMe)Cl] complex 3. In contrast to 1, which gives strongly adherent polymeric [Ru(bpy)(CO)(2)](n) molecular films, electrochemical reduction of 2 and 3 forms dimers 5 and 6 by a one-electron reduction process accompanied by loss of a chloro ligand. Complexes 2, 3, 5, and 6 function as efficient homogeneous electrocatalysts for the selective reduction of CO2 to CO (95-97% faradaic yield) in aqueous acetonitrile.

  DOI：

  10.1021/ic9701975
• 作为试剂：
  描述：

  二氧化碳 在 [Ru(C₁₀H₈N₂)(CO)2(CO₂CH₃)]2 作用下， 以 not given 为溶剂， 生成 一氧化碳
  参考文献：
  名称：

  Selective Synthesis and Electrochemical Behavior of trans(Cl)- and cis(Cl)-[Ru(bpy)(CO)₂Cl₂] Complexes (bpy = 2,2‘-Bipyridine). Comparative Studies of Their Electrocatalytic Activity toward the Reduction of Carbon Dioxide

  摘要：

  A synthetic procedure for the selective preparation (ca. 75% isolated yield) of trans(Cl)- and cis(Cl)-[Ru(bpy)(CO)(2)Cl-2] complexes 1 and 2, using an oligomeric [Ru(CO)(2)Cl-2](n) precursor, is described. The synthetic methodology also gives access to the cis(CO)-[Ru(bpy)(CO)(2)(C(O)OMe)Cl] complex 3. In contrast to 1, which gives strongly adherent polymeric [Ru(bpy)(CO)(2)](n) molecular films, electrochemical reduction of 2 and 3 forms dimers 5 and 6 by a one-electron reduction process accompanied by loss of a chloro ligand. Complexes 2, 3, 5, and 6 function as efficient homogeneous electrocatalysts for the selective reduction of CO2 to CO (95-97% faradaic yield) in aqueous acetonitrile.

  DOI：

  10.1021/ic9701975