| 848491-76-9

• CAS: 848491-76-9
• 化学式: C₁₂H₁₇Cl₃CrNS₂
• 分子量: 397.761
• InChiKey: IMQSPVDHEUPQSJ-HSDORCTDSA-K

反应信息

• 作为产物：
  描述：

  trichlorotris(tetrahydrofuran)chromium(III) 、 N-(2-ethylsulfanylethyl)-1-(2-methylsulfanylphenyl)methanimine 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Chromium imine and amine complexes as homogeneous catalysts for the trimerisation and polymerisation of ethylene

  摘要：

  Cr(III) complexes of tridendate imine and amine ligands with N, P, O, S donor atoms 1 and 2 have been prepared and tested as catalysts in the oligomerisation and polymerisation of ethylene giving excellent selectivity towards 1-hexene and polymerisation to polyethylene when activated with cocatalysts. X-ray structure analyses of the precatalysts 1a-c, 1i, and 2b are investigated. The metal-ligand binding in 1a and 1b is nearly the same, which leads to similar catalytic activities of these precatalysts. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.09.080