mer-tricarbonyldiiodo(triethyl phosphite)iron(II) | 1196130-83-2

• 英文名称: mer-tricarbonyldiiodo(triethyl phosphite)iron(II)
• 英文别名: mer-FeI2(CO)3(P(OEt)3)；mer-Fe(iodide)2(carbonyl)3(triethyl phosphite)
• CAS: 1196130-83-2
• 化学式: C₉H₁₅FeI₂O₆P
• 分子量: 559.844
• InChiKey: VVYYOIIMBAWGPG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  diiodotetracarbonyliron(II) 、 亚磷酸三乙酯 以 正己烷 为溶剂， 以68%的产率得到mer-tricarbonyldiiodo(triethyl phosphite)iron(II)
  参考文献：
  名称：

  Synthesis and Mössbauer Characterization of Octahedral Iron(II) Carbonyl Complexes FeI₂(CO)₃L and FeI₂(CO)₂L₂: Developing Models of the [Fe]-H₂ase Active Site

  摘要：

  A series of mono- and disubstituted complexes, FeI2(CO)(x)L4-x, x = 2 or 3, is conveniently accessed from simple mixing of N-heterocyclic carbenes, phosphines, and aromatic amines with FeI2(CO)(4), first reported by Hieber in 1928. The highly light sensitive complexes yield to crystallization and X-ray diffraction studies for six complexes showing them to be rudimentary structural models of the monoiron hydrogenase, [Fe]-H(2)ase or Hmd, active site in native (Fe-II(CO)(2)) or CO-inhibited (Fe-II(CO)(3)) states. Diatomic ligand (nu(CO)) vibrational and Mossbauer spectroscopies are related to those reported for the Hind active site. The importance of a serial approach for relating such parameters in model compounds to low spin Fe-II in the diverse ligation of enzyme active sites is stressed.

  DOI：

  10.1021/ic9017882