trans-[Rh(Cl)(C2H4)(tBu2PH)2] | 146616-68-4

• 英文名称: trans-[Rh(Cl)(C2H4)(tBu2PH)2]
• CAS: 146616-68-4
• 化学式: C₁₈H₄₂ClP₂Rh
• 分子量: 458.837
• InChiKey: FEXJQMAKQIMQRQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-[Rh(Cl)(C2H4)(tBu2PH)2] 以 正辛烷 为溶剂， 以100%的产率得到[{Rh(μ-Cl)(PtBu₂H)₂}₂]
  参考文献：
  名称：

  Synthese, charakterisierung und reaktivität heterodinuklearer komplexe: [(CO)4(μ-PtBu2)Rh(CO)L](Fe-Rh) (L = CO2, HPtBu2), [(CO)3,Co(μ-H)(μ-PtBu2)Rh(CO)(HPtBu2)](Co-Rh)

  摘要：

  [Rh2(mu-Cl)2(HPtBU2)4] (2) reacts with K[Co(CO)4] and PPN[FeH(CO)4] to give the heterobinuclear complexes [(CO)3Co(mu-H)(mu-PtBU2)Rh(CO)(HPtBu2)] (5) and [(CO)4Fe(mu-PtBU2)Rh (CO)(HPtBu2)] (4), respectively. Treatment of 5 with KH results in its anion, which is isolated as PPN[(CO)3Co(mu-PtBU2)Rh(CO)(HPtBU2)] (PPN[8]). Substitution of one carbonyl ligand on the Co atom occurs with PPh3. The structure of the resulting CoMPleX [(CO)2(PPh3)Co(mu-H)(mu-PtBU2) Rh-(CO)(HPtBu2)] (7) has been determined by an X-ray diffraction study. Hydroformulation reactions with these complexes are reported.

  DOI：

  10.1016/0022-328x(92)85077-a
• 作为产物：
  描述：

  bis(ethylene)rhodium(I) chloride dimer 、 二-叔丁基膦 以 正戊烷 为溶剂， 以77%的产率得到trans-[Rh(Cl)(C2H4)(tBu2PH)2]
  参考文献：
  名称：

  Synthese, charakterisierung und reaktivität heterodinuklearer komplexe: [(CO)4(μ-PtBu2)Rh(CO)L](Fe-Rh) (L = CO2, HPtBu2), [(CO)3,Co(μ-H)(μ-PtBu2)Rh(CO)(HPtBu2)](Co-Rh)

  摘要：

  [Rh2(mu-Cl)2(HPtBU2)4] (2) reacts with K[Co(CO)4] and PPN[FeH(CO)4] to give the heterobinuclear complexes [(CO)3Co(mu-H)(mu-PtBU2)Rh(CO)(HPtBu2)] (5) and [(CO)4Fe(mu-PtBU2)Rh (CO)(HPtBu2)] (4), respectively. Treatment of 5 with KH results in its anion, which is isolated as PPN[(CO)3Co(mu-PtBU2)Rh(CO)(HPtBU2)] (PPN[8]). Substitution of one carbonyl ligand on the Co atom occurs with PPh3. The structure of the resulting CoMPleX [(CO)2(PPh3)Co(mu-H)(mu-PtBU2) Rh-(CO)(HPtBu2)] (7) has been determined by an X-ray diffraction study. Hydroformulation reactions with these complexes are reported.

  DOI：

  10.1016/0022-328x(92)85077-a