[Ru(η5-indenyl){κ2(P,C)-iPr2PCH2CH(SMe)CH2}(PPh3)] | 1447959-71-8

• 英文名称: [Ru(η5-indenyl){κ2(P,C)-iPr2PCH2CH(SMe)CH2}(PPh3)]
• 英文别名: [Ru(η⁵-indenyl){κ²(P,C)-iPr₂PCH₂CH(SMe)CH₂}(PPh₃)]
• CAS: 1447959-71-8
• 化学式: C₃₇H₄₄P₂RuS
• 分子量: 683.84
• InChiKey: XPLHBAGYAMJYHY-RLNSOXNHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲硫醇 、 [Ru(η⁵-indenyl){κ³(P,C,C)-iPr₂PCH₂CHCH₂}(PPh₃)][BPh₄] 在 sodium hydroxide 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以72%的产率得到[Ru(η5-indenyl){κ2(P,C)-iPr2PCH2CH(SMe)CH2}(PPh3)]
  参考文献：
  名称：

  Organoruthenium Complexes Containing New Phosphorus–Carbon and Phosphorus–Carbon–Sulfur Ligands Generated in the Coordination Sphere by Nucleophilic Addition Reactions

  摘要：

  The reaction of the dimeric complex [RuCl(mu-Cl)(eta(6)-C10H14)](2) (C10H14 = p-cymene) with an excess of allyldiisopropylphosphane (ADIP) leads to the complex [RuCl(eta(6)-C10H14)(kappa(2)(P,C)-iPr(2)PCH(2)CH(iPr(2)PCH(2)CH=CH2)CH2}](+) (1(+)), which presents a new bidentate kappa(2)(P,C) ligand. The same cationic complex can be prepared by nuclephilic attack of 1 equiv of the free ADIP at the coordinated kappa(3)(P,C,C)-iPr(2)PCH(2)CH=CH2 ligand in [RuCl(eta(6)-C10H14){kappa(3)(P,C,C)-iPr(2)PCH(2)CH=CH2}](+) (3(+)). Addition of different phosphane ligands to complex 3(+) allows to the synthesis of ruthenium complexes with new bidentate ligands kappa(2)(P,C). The unusual complexes [Ru{kappa(3)(P,C,S)-iPr(2)PCH(2)CH(SR)CH2}(eta(6)-C10H14)](+) (11a-c(+)) containing new kappa(3)(P,C,S) ligands can be obtained by the reaction of 3(+) with anionic nucleophiles RS-. For comparative purposes, the indenyl complex [Ru(eta(5)-C9H7){kappa(3)(P,C,C)-iPr(2)PCH(2)CH=CH2}(PPh3)](+) (8(+)) has been also prepared and differences in the reactivities of cationic complexes 3(+) and 8(+) toward nucleophiles are pointed out.

  DOI：

  10.1021/om400487g