| 211488-35-6

• CAS: 211488-35-6
• 化学式: C₂₈H₂₆FeO₃PRh
• 分子量: 600.239
• InChiKey: GEVZXPXDVYIVFT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1′-(diphenylphosphino)ferrocene-1-carboxylic acid 、 以 丁酮 为溶剂， 以42%的产率得到
  参考文献：
  名称：

  Stepnicka, Petr; Cisarova, Ivana, Journal of the Chemical Society, Dalton Transactions, 1998, # 7, p. 2807 - 2812

  摘要：

  DOI：
• 作为产物：
  描述：

  二苯基膦基二茂铁 、 acetylacetonatodicarbonylrhodium(l) 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Electron density manipulation in rhodium(I) phosphine complexes: structure of acetylacetonatocarbonylferrocenyl- diphenylphosphinerhodium(I)

  摘要：

  The title complex [Rh(acac)(CO)(PPh(2)Fc)] (acac = acetylacetonato, PPh(2)Fc = ferrocenyldiphenylphosphine), was obtained in acetone by reaction of the tertiary phosphine with [Rh(acac)(CO)(2)] and was characterised by IR spectroscopy, H-1 and P-31 NMR and single crystal X-ray crystallography. This is a rare example illustrating the incorporation of the ferrocenyl moiety in a monodentate tertiary phosphine complex of rhodium(I). It crystallises in the triclinic space group P-I with two independent molecules in the asymmetric unit and refined to R = 2.40% from 5215 reflections. The independent molecules, showing the usual square planar geometry, differ mainly in the rotation mode of the asymmetric phosphine around the Rh-P bond and a slight deviation in the Rh-CO bond from linearity, which was correlated with IR data. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00049-7