[GeCl(4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone)2H]*(hexane) | 1143584-50-2

• 英文名称: [GeCl(4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone)2H]*(hexane)
• CAS: 1143584-50-2
• 化学式: C₆H₁₄*C₅₂H₇₅ClGeN₂O₂
• 分子量: 954.4
• InChiKey: YGQQXVUMRIACPP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [GeCl(4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone)2H]*(hexane) 在 O₂ 作用下， 以 丙酮 为溶剂， 以58.5%的产率得到[GeCl(4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone)2]
  参考文献：
  名称：

  New Germanium Complexes Containing Ligands Based on 4,6‐Di‐ tert ‐butyl‐ N ‐(2,6‐diisopropylphenyl)‐ o ‐iminobenzoquinone in Different Redox States

  摘要：

  AbstractThe exchange reaction of lithium o‐amidophenolate, (AP)Li2, derived from the reaction of 4,6‐di‐tert‐butyl‐N‐(2,6‐diisopropylphenyl)‐o‐iminobenzoquinone (imQ) with GeCl4 in hexane or thf leads to (AP)2Ge (1) (AP is a dianion of imQ). The latter was also obtained by the interaction of GeCl2·dioxane and (ISQ)Li in toluene (ISQ is a radical anion of imQ). The reaction of (AP)Li2 with GeCl2·dioxane in thf results in the formation of germylene 2, [(AP)Ge (2)], which reduces neutral imQ to give compound 1. The exposure of 1 in thf to anhydrous HCl in a 1:1 molar ratio leads to its o‐aminophenolato derivative, (AP)(APH)GeCl (3). Free imQ inserts into the Ge–H bond of (C6F5)3GeH in thf to give (C6F5)3Ge(APH) (4). It is another way of obtaining complexes with protonated ligands such as APH. Compound 3 can be easily oxidized by air to form the stable paramagnetic complex (AP)(ISQ)GeCl (5). Complexes 1 and 3–5 were structurally investigated by using single‐crystal X‐ray diffraction.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

  DOI：

  10.1002/ejic.200701115
• 作为产物：
  描述：

  [Ge(4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone)] 以 四氢呋喃 为溶剂， 生成 [GeCl(4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone)2H]*(hexane)
  参考文献：
  名称：

  New Germanium Complexes Containing Ligands Based on 4,6‐Di‐ tert ‐butyl‐ N ‐(2,6‐diisopropylphenyl)‐ o ‐iminobenzoquinone in Different Redox States

  摘要：

  AbstractThe exchange reaction of lithium o‐amidophenolate, (AP)Li2, derived from the reaction of 4,6‐di‐tert‐butyl‐N‐(2,6‐diisopropylphenyl)‐o‐iminobenzoquinone (imQ) with GeCl4 in hexane or thf leads to (AP)2Ge (1) (AP is a dianion of imQ). The latter was also obtained by the interaction of GeCl2·dioxane and (ISQ)Li in toluene (ISQ is a radical anion of imQ). The reaction of (AP)Li2 with GeCl2·dioxane in thf results in the formation of germylene 2, [(AP)Ge (2)], which reduces neutral imQ to give compound 1. The exposure of 1 in thf to anhydrous HCl in a 1:1 molar ratio leads to its o‐aminophenolato derivative, (AP)(APH)GeCl (3). Free imQ inserts into the Ge–H bond of (C6F5)3GeH in thf to give (C6F5)3Ge(APH) (4). It is another way of obtaining complexes with protonated ligands such as APH. Compound 3 can be easily oxidized by air to form the stable paramagnetic complex (AP)(ISQ)GeCl (5). Complexes 1 and 3–5 were structurally investigated by using single‐crystal X‐ray diffraction.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

  DOI：

  10.1002/ejic.200701115