{bismuth nitrate bis(pentacarbonyl manganese)} | 149730-28-9

• 英文名称: {bismuth nitrate bis(pentacarbonyl manganese)}
• CAS: 149730-28-9
• 化学式: C₁₀BiMn₂O₁₀*NO₃
• 分子量: 660.965
• InChiKey: RYQYQPJDWGOBHP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bismuth (III) nitrate pentahydrate 、 羰基镁 在 NaK 作用下， 以 四氢呋喃 为溶剂， 以25%的产率得到{bismuth nitrate bis(pentacarbonyl manganese)}
  参考文献：
  名称：

  Synthetic and structural studies on organotransition metal–bismuth nitrates

  摘要：

  The reaction between Bi(NO3)3.5H2O and 2 equivalents of K[Fe(CO)2(eta-C5H5)] affords the iron-bismuth complex [Bi(NO3){Fe(CO)2(eta-C5H5)}2] 1 which was characterised by X-ray crystallography. Complex 1 comprises a bismuth atom in a trigonal-pyramidal co-ordination geometry bonded to two Fe(CO)2(eta-C5H5) fragments and the oxygen atom of a monodentate nitrate group. In addition there is a longer secondary intermolecular contact between the bismuth and a nitrate oxygen of an adjacent molecule which is approximately trans to the primary Bi-O bond. The complexes [Bi(NO3)(ML(n))2] [ML(n) = Fe(CO)2(eta-C5H4Me) 2, Ru(CO)2(eta-C5H5) 3, Mo(CO)3(eta-C5H5) 6, Mo(CO)3(eta-C5H4Me) 7, W(CO)2(eta-C5H5) 8, W(CO)3(eta-C5H4Me) 9 or Cr(CO)3(eta-C5H5) 10] have also been prepared and characterised by spectroscopic and analytical methods. Data are also presented on the synthesis and characterisation of the ruthenium complexes [Bi{Ru(CO)2(eta-C5H5)}3] 4 and [BiCl{Ru(CO)2(eta-C5H5)}2] 5 and on the reactions between bismuth nitrate and 2 equivalents of K[Mn(CO)5] or K[Co(CO)3(PR3)] (R = Ph or OPh).

  DOI：

  10.1039/dt9930001201