Fc(SiMe2)2Cl | 260995-69-5

• 英文名称: Fc(SiMe2)2Cl
• CAS: 260995-69-5
• 化学式: C₁₄H₂₁ClFeSi₂
• 分子量: 336.792
• InChiKey: SRKKRGSNSZSSGU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  溴苯 、 Fc(SiMe2)2Cl 在 Mg 作用下， 以 四氢呋喃 为溶剂， 以45%的产率得到
  参考文献：
  名称：

  Synthesis, Spectroscopy, Electrochemical Characterization, and Nonlinear Optical Properties of Ferrocenyloligosilanes:  FcSi_nMe_2n(C₆H₅) (n = 1−6) and FcSi₂Me₄(C₆H₄-X) (X = m-CF₃, p-Cl, p-Br, p-OMe, p-NMe₂, p-CHC(CN)₂)

  摘要：

  New ferrocenyloligosilylene aryl complexes have been synthesized, FcSi(n)Me(2n)C(6)H(5) (n = 1-6) and FcSi(2)Me(4){C6H4-X) (X = m-CF3. p-Cl, p-Br, p-OMe, p-NMe2, p-CH=C(CN)(2)). The complexes have been evaluated with respect to their electrochemical redox and NLO hyperpolarizability properties. All complexes possess oxidation potentials that reflect, systematically but weakly, the various substituents on the aryl group, thereby indicating an aryl-ferrocenyl interaction via the silicon chains. However, hyperpolarizabilities of the complexes are generally similar to those of the corresponding substituted benzenes, with the exception of the most electron-withdrawing substituents, p-Cl and p-CH=C(CN)(2).

  DOI：

  10.1021/om990733w
• 作为产物：
  描述：

  正丁基锂 、 1-(chloromercuri)ferrocene 、 1,2-二氯四甲基二硅烷 以 环己烷 为溶剂， 以30%的产率得到Fc(SiMe2)2Cl
  参考文献：
  名称：

  Synthesis, Spectroscopy, Electrochemical Characterization, and Nonlinear Optical Properties of Ferrocenyloligosilanes:  FcSi_nMe_2n(C₆H₅) (n = 1−6) and FcSi₂Me₄(C₆H₄-X) (X = m-CF₃, p-Cl, p-Br, p-OMe, p-NMe₂, p-CHC(CN)₂)

  摘要：

  New ferrocenyloligosilylene aryl complexes have been synthesized, FcSi(n)Me(2n)C(6)H(5) (n = 1-6) and FcSi(2)Me(4){C6H4-X) (X = m-CF3. p-Cl, p-Br, p-OMe, p-NMe2, p-CH=C(CN)(2)). The complexes have been evaluated with respect to their electrochemical redox and NLO hyperpolarizability properties. All complexes possess oxidation potentials that reflect, systematically but weakly, the various substituents on the aryl group, thereby indicating an aryl-ferrocenyl interaction via the silicon chains. However, hyperpolarizabilities of the complexes are generally similar to those of the corresponding substituted benzenes, with the exception of the most electron-withdrawing substituents, p-Cl and p-CH=C(CN)(2).

  DOI：

  10.1021/om990733w