trans-dibromobis(5-tert-butylpyrazole-N2)copper(II) | 393564-40-4

• 英文名称: trans-dibromobis(5-tert-butylpyrazole-N2)copper(II)
• CAS: 393564-40-4
• 化学式: C₁₄H₂₄Br₂CuN₄
• 分子量: 471.725
• InChiKey: UOYMYSXUKWRBHR-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  copper(ll) bromide 、 3-叔丁基-1H-吡唑 以 二氯甲烷 、 丙酮 、 正戊烷 为溶剂， 生成 trans-dibromobis(5-tert-butylpyrazole-N2)copper(II)
  参考文献：
  名称：

  Two complexes of CuBr₂with 5-tert-butylpyrazole

  摘要：

  trans-Dibromobis(5-tert-butylpyrazole-N-2)copper(II), trans[CuBr2 (Hpz(tBu))(2)] (Hpz(tBu) is 5-tert-butylpyrazole, C7H12N2), exhibits a distorted square-planar geometry with a significant tetrahedral twist, while trans-dibromotetrakis(5-tert-butylpyrazole-N-2)copper(II), trans-[CuBr2(Hpz(tBu))(4)], adopts a distorted octahedral geometry across a crystallographic inversion centre. Both compounds exhibit intramolecular N-H . . . Br hydrogen-bonding interactions.

  DOI：

  10.1107/s0108270101012653