| 500305-63-5

• CAS: 500305-63-5
• 化学式: C₂₃H₃₃N₂Pd
• 分子量: 443.948
• InChiKey: CFFFDRHZNOUNLV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-甲基-2-丁醇 、 tetraaqua palladium(II) perchlorate 、 4,4'-二叔丁基-2,2'-二吡啶 以 高氯酸 为溶剂， 生成
  参考文献：
  名称：

  摘要：

  Reactions of 2-methyl-2-propanol, 2-methyl-2-butanol, 2-methyl-2-pentanol, 1-methyl-1-cyclohexanol, and 1-ethyl-1-cyclohexanol with palladium(H) tetraaqua complex in a perchloric acid medium give carbonyl and aromatic compounds, as well as the corresponding palladium pi-allyl complexes. The complexes were isolated from the reaction mixtures by way of formation of 2,2'-bipyridine complexes and characterized by the elemental analyses and H-1 and C-13 NMR spectra. The main direction of transformation of acyclic alcohols is formation of complexes with no alkyl substituents at the central carbon atom of the allyl ligand; with cyclic alcohols, exocyclic complexes are formed.

  DOI：

  10.1023/a:1020446710393