[Ni(5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,7,11,14-tetraene)Cl2] | 381221-57-4

• 英文名称: [Ni(5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,7,11,14-tetraene)Cl2]
• CAS: 381221-57-4
• 化学式: C₁₄H₂₄Cl₂N₄Ni
• 分子量: 377.967
• InChiKey: XGUITIRYVDKFCC-RRCMSLSNSA-L

反应信息

• 作为产物：
  描述：

  乙二胺 、 乙酰丙酮 、 nickel dichloride 在 aq. HCl 作用下， 以 乙醇 为溶剂， 以72%的产率得到[Ni(5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,7,11,14-tetraene)Cl2]
  参考文献：
  名称：

  SYNTHESIS AND SPECTRAL STUDIES OF TRANSITION METAL COMPLEXES WITH 5,7,12,14-TETRAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECA-4,7,11,14-TETRAENE, A FOURTEEN-MEMBERED TETRADENTATE MACROCYCLIC LIGAND

  摘要：

  Complexes of Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Pd(II) and Cu(II) with a fourteen-membered macrocyclic ligand have been prepared and characterized by magnetic moment, infrared, electronic and EPR spectral studies. All of complexes were found to have six-coordinate geometry and are of the high-spin type except the Pd(II) complex which is four-coordinate, square-planar and diamagnetic.

  DOI：

  10.1081/sim-100106858