((η6-C6H5)Cr(CO)3Me2Si)(GeMe3)(PbMe3)CH | 1227772-96-4

• 英文名称: ((η6-C6H5)Cr(CO)3Me2Si)(GeMe3)(PbMe3)CH
• CAS: 1227772-96-4
• 化学式: C₁₈H₃₀CrGeO₃PbSi
• 分子量: 654.306
• InChiKey: UVMUALCHGYLDFS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  phenyldimethylsilyl(trimethylgermyl)(trimethylplumbyl)methane 、 六羰基铬 以 四氢呋喃 、 二丁醚 为溶剂， 以42%的产率得到((η6-C6H5)Cr(CO)3Me2Si)(GeMe3)(PbMe3)CH
  参考文献：
  名称：

  Arenechromiumtricarbonyl complexes of silyl(germyl)(stannyl)- and silyl(germyl)(plumbyl)methanes including the unexpected formation of arenechromiumtricarbonyldimethylsilanol, (η6-C6H5)Cr(CO)3SiMe2OH

  摘要：

  Treatment of PhMe2SiCH2GeMe3 (1) with t-BuLi followed by addition of Me3ECl, E = Sn, Pb, results in the formation of phenylsilyl(germyl) stannyl- and phenylsilyl(germyl)plumbyl-methanes, PhMe2Si(Me3Ge)(EMe3) CH, E = Sn (2), Pb (3). The thermal reaction of 1, 2 and 3 with Cr(CO)(6) yields the corresponding aryl-Cr(CO)(3) analogs, {(eta(6)-C6H5)Cr(CO)(3)}Me2Si(Me3Ge)CH2 (4) and {(eta(6)-C6H5)Cr(CO)(3)}Me2Si(Me3Ge)(EMe3) CH, E = Sn (5), Pb (6). The thermal treatment of 2 with Cr(CO)(6) in a wet THF/di-n-butyl ether mixture results in the formation of the arenechromiumtricarbonyl silanol {(eta(6)-C6H5)Cr(CO)(3)}Me2SiOH (7) which exhibits amphiphilic character, forming H-bonded chains in the solid state in a head-to-head arrangement of the areneCr(CO)(3) units. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.01.027