[ruthenium(III)(1,5:10,14-dimetheno-[1,4,8,11]-tetraazacyclotetradeca-1,3,5,6,8,10,12,14,15,17-decene)Cl2]Cl | 443965-19-3

• 英文名称: [ruthenium(III)(1,5:10,14-dimetheno-[1,4,8,11]-tetraazacyclotetradeca-1,3,5,6,8,10,12,14,15,17-decene)Cl2]Cl
• CAS: 443965-19-3
• 化学式: C₁₆H₁₂Cl₂N₄Ru*Cl
• 分子量: 467.727
• InChiKey: OTBPWFYNTDADHC-ZXXKYRHXSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  草酸醛 、 三氯化钌 、 间苯二胺 以 乙醇 为溶剂， 以56%的产率得到[ruthenium(III)(1,5:10,14-dimetheno-[1,4,8,11]-tetraazacyclotetradeca-1,3,5,6,8,10,12,14,15,17-decene)Cl2]Cl
  参考文献：
  名称：

  SYNTHESIS AND SPECTRAL STUDIES OF Pd(II), Pt(II), Ir(III), AND Ru(III) COMPLEXES WITH 12–16 MEMBERED TETRADENTATE MACROCYCLIC LIGANDS

  摘要：

  Pd(II), Pt(II), Ir(III) and Ru(III) complexes have been synthesized by the template method and characterized on the basis of elemental analyses, molar conductance, magnetic susceptibility measurements and electronic spectral studies. The complexes have the compositions [M(ligand)]Cl-2 (M = Pd or Pt) and [M'(ligand)Cl-2]Cl (M'=Ru and Ir) and (ligands=1,5:11,15-dimetheno-2,4,10,12-tetramethyl-[1,5,9,13]-tetraazacyclohexadeca-1,3,5,6,10,11,13,15,16,20-decene (L-1), 1,5:10,14-dimetheno-[1,4,8,11]-tetraazacyclotetradeca-3,5,6,8,10,12,-1,4,15,17-decene (L-2), dibenzo-[b,i]-8,10,19,21-tetramethyl-[1,5,8,12]-tetraazacyclotetradeca- 1,3,5,7,10,12,14,16,18,21-decene (L-3) and dibenzo-[b,h]-1,4,7,10-tetraazacyclododeca-1,3,5,7,9,11,13,15,17,19-decene (L-4)). The complexes of Pd(II) and Pt(II) are square-planar in geometry. The Ru(III) and Ir(III) complexes arc six-coordinate and octahedral.

  DOI：

  10.1081/sim-120003794