| 1035666-18-2

• CAS: 1035666-18-2
• 化学式: C₄₅H₅₁Ge₂N₅O₆Si₃
• 分子量: 987.366
• InChiKey: KECOMMIXKPTIEA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis[bis(trimethylsilyl)amino]germanium(II) 、 冠6烯 以 苯 为溶剂， 以41%的产率得到
  参考文献：
  名称：

  Synthesis and crystal structure of a germanium(II) calix[6]arene containing unusual diamidosilyl ether groups

  摘要：

  The reaction of Ge[N(SiMe3)(2)](2) with calix[6]arene furnishes a novel macrocyclic product having two divalent germanium atoms incorporated into a Ge2NO rhombus which contains a mu(2)-oxygen atom and a mu(2)-NH2 group. The crystal structure of the product indicates the presence of a conformationally rigid molecule where three of the six oxygen atoms of the calix[6]arene are bound to the germanium atoms while the remaining three have been converted into -OSiMe3 or unusual -OSi(H)(NH2)(2) groups. Spectral (H-1, C-13, and Si-29 NMR) data in solution are consistent with the solid-state structure and indicate the germanium calix[6]arene retains its structure in solution. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.02.027