| 261773-27-7

• CAS: 261773-27-7
• 化学式: C₉₃H₂₄MoO₃P₂
• 分子量: 1347.1
• InChiKey: NCPUIZZZVWWPDI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  fac-Mo(CO)3(1,2-bis(diphenylphosphino)benzene)(CH3CN) 、 足球烯 以 氯苯 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  Synthesis and Crystal Structures of Two Isomerically Pure Organotransition-Metal [60]Fullerene Derivatives Containing dppb Ligands:  mer-M(CO)₃(dppb)(η²-C₆₀) (M = Mo, W)

  摘要：

  The reaction of M(CO)(3)(CH3CN)(3) (M = Mo, W) with an equimolar quantity of 1,2-bis(diphenylphosphino)benzene (dppb) results in formation of fac-M(CO)(3)(dppb) (CH3CN) (1, M = Mo, 73%; 2, M = W, 62%). Interaction of 1 or 2 with [60]fullerene in chlorobenzene at about 80 degrees C gives the isomerically pure isomers mer-M(CO)(3)(dppb)(eta(2)-C-60) (3, M = Mo, 76%; 4, M = W, 66%). All the new compounds 1-4 have been characterized by elemental analysis and spectroscopic methods, as well as by single-crystal X-ray diffraction analysis for 3 and 4.

  DOI：

  10.1021/om990975w