(nitrato-O)(nitrato-O,O')(η6-hexamethylbenzene)ruthenium(II) | 142801-96-5

• 英文名称: (nitrato-O)(nitrato-O,O')(η6-hexamethylbenzene)ruthenium(II)
• CAS: 142801-96-5
• 化学式: C₁₂H₁₈N₂O₆Ru
• 分子量: 387.355
• InChiKey: SDFGDNSQXAGQGE-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [RuCl2(hexamethylbenzene)]2 、 silver nitrate 以 丙酮 为溶剂， 以84%的产率得到(nitrato-O)(nitrato-O,O')(η6-hexamethylbenzene)ruthenium(II)
  参考文献：
  名称：

  Crystal Structures and Characterizations of (Nitrato-O)(Nitrato-O,O′)(η⁶-Hexamethylbenzene)Ruthenium(II) and Di(Trifluoroacetato-O)(H₂O-O)(η⁶-Hexamethylbenzene) Ruthenium(II)

  摘要：

  The title complexes [(HMB)Ru(NO3)(2)] (HMB = eta(6)-C6Me6) (1) and [(HMB)Ru(O2CCF3)(2)(H2O)] (2) were spectroscopically characterized and their structures were determined by single-crystal diffraction analysis. In both compounds, the Ru atom is eta(6)-coordinated to a hexamethylbenzene ring and three oxygen donor atoms in a "three-legged piano stool" arrangement. In the asymmetric unit of 1, ruthenium atom is coordinated to two nitrato ligands, one of which is eta(1)-O coordinated and the second bidentate via both oxygen atoms; while in the symmetric unit of 2, two disordered trifluoroacetate ligands are monodentate, symmetrically bound to the ruthenium atom, and the pseudo-octahedral geometry is completed by an oxygen atom from a H2O molecule, which is hydrogen-bonded to both acetate ligands.

  DOI：

  10.1080/15533170500360164