[LaBr2((N(isopropyl)CHC(Me)CH(Ph))2)Li(DME)]2 | 848487-01-4

• 英文名称: [LaBr2((N(isopropyl)CHC(Me)CH(Ph))2)Li(DME)]2
• CAS: 848487-01-4
• 化学式: C₆₀H₈₈Br₄La₂Li₂N₄O₄
• 分子量: 1540.69
• InChiKey: BUMUGACZRIXFJW-UHEARRNYSA-J

反应信息

• 作为产物：
  描述：

  lanthanum(III)-bromide tetrahydrofurane solvate (1/5) 、 以 乙二醇二甲醚 为溶剂， 以68%的产率得到[LaBr2((N(isopropyl)CHC(Me)CH(Ph))2)Li(DME)]2
  参考文献：
  名称：

  Between Enamide and Azaallyl Structures:  Novel Flexible N-Chelate Ligands in the Lanthanide Chemistry

  摘要：

  Novel types of hexa-1,5-diene-1,6-diamide neodymium complexes were prepared from the corresponding neodymium bromide NdBr3(THF)(3.5) with the appropriate dilithium hexa-1,5-diene-1,6-diamide reagent. The molecular structures of the new complexes revealed that the chelating hexa-1,5-diene-1,6-diamide can be bound either as an enamide or as an azaallyl-type ligand.

  DOI：

  10.1021/om049655p