| 265642-28-2

• CAS: 265642-28-2
• 化学式: C₂₇H₄₅IrN₂
• 分子量: 589.888
• InChiKey: ULWWZBBWDVLXNI-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  三氟甲磺酸 、 以 二氯甲烷-D2 为溶剂， 以71%的产率得到
  参考文献：
  名称：

  Unsymmetrically Substituted Iridium(III)−Carbene Complexes by a CH-Activation Process

  摘要：

  The synthesis of the metalhydride Cp*(L')IrH+OTf- (L' = 1-(2-cyclohexenyl)-3-cyclohexylimidazolin-2-ylidene, OTf = OSO2CF3) is achieved by a cyclohexane to cyclohexene transformation at the N-heterocyclic carbene ligand based on a CH-activation/beta-hydrogen migration process at the Ir(III) center under mild conditions. The synthetic route to Cp*(L')IrH+OTf- and NMR spectroscopic and X-ray structural data are presented.

  DOI：

  10.1021/om990804r
• 作为产物：
  描述：

  、 甲基氯化镁 以 四氢呋喃 为溶剂， 以77%的产率得到
  参考文献：
  名称：

  Unsymmetrically Substituted Iridium(III)−Carbene Complexes by a CH-Activation Process

  摘要：

  The synthesis of the metalhydride Cp*(L')IrH+OTf- (L' = 1-(2-cyclohexenyl)-3-cyclohexylimidazolin-2-ylidene, OTf = OSO2CF3) is achieved by a cyclohexane to cyclohexene transformation at the N-heterocyclic carbene ligand based on a CH-activation/beta-hydrogen migration process at the Ir(III) center under mild conditions. The synthetic route to Cp*(L')IrH+OTf- and NMR spectroscopic and X-ray structural data are presented.

  DOI：

  10.1021/om990804r