3-methyl-2,8-bis(N,N-dimethyl-N-chloromethylammonium)-7-chlorohydro-closo-decaborane | 948038-94-6

• 英文名称: 3-methyl-2,8-bis(N,N-dimethyl-N-chloromethylammonium)-7-chlorohydro-closo-decaborane
• 英文别名: 3-CH3-2,8-[N(CH3)2(CH2Cl)]2-7-Cl-B10H6
• CAS: 948038-94-6
• 化学式: C₇H₂₅B₁₀Cl₃N₂
• 分子量: 351.758
• InChiKey: IDYPWXVMEDAWHD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(tetrabutylammonium)-decahydro-closo-decaborate 、 N,N-二甲基甲酰胺 、 三氯氧磷 以 乙腈 为溶剂， 以70%的产率得到2,7-bis(N,N-dimethyl-N-chloromethylammonium)octahydro-closo-decaborane
  参考文献：
  名称：

  Interaction of closo-decaborate anion B10H 10 2− with iminium salts

  摘要：

  The interaction of closo-decaborate anions with iminium salts, either formed in situ or introduced into the reaction as individual compounds, has been studied. The reaction leads to products with an exopolyhedral boron-nitrogen bond. The formation of compounds with exopolyhedral boron-chlorine and boron-carbon bonds is also possible. The crystal structures of [NMe2(CH2Cl)](2)B10H8 and 3-CH3-2,8-[NMe2(CH2Cl)](2)-7-ClB10H6 have been studied.

  DOI：

  10.1134/s003602360610007x