摘要:
Reaction of platinum(II) salts with 5-ferrocenylpyrimidine (FcPM) afforded cis-[Pt(NH3)(2)(FcPM)(2)](PF6)(2) (1), trans-[Pt(NH3)(2)(FcPM)(2)](PF6)(2) (2), cis-[PtCl2(FcPM)(2)] (3), and cis-[PtCl2(DMSO)(FcPM)] (4): their spectroscopic and electrochemical properties were investigated. Complexes 1 and 2 were structurally characterized by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.