| 861709-58-2

• CAS: 861709-58-2
• 化学式: C₄₂H₄₂Li₂N₄
• 分子量: 616.704
• InChiKey: AXDSSGFJAYZFOI-SUHUSKRKSA-N

反应信息

• 作为反应物：
  描述：

  、 三氯化硼 以 甲苯 、 正戊烷 为溶剂， 以90%的产率得到2-(phenylamidoborondichloride-phenyl)methyl-dimethylaminobenzene
  参考文献：
  名称：

  Synthesis and Characterization of Novel Intramolecularly Base-stabilized Boron Halides. Molecular Structures of 1-X2BOCR1R2-2-NMe2C6H4 [R1 = R2 = Ph, X = Cl or F; R1 = R2 = Cy, X = Cl] and [1-LiN(Ph)C(H)Ph-2-NMe2C6H4]2

  摘要：

  AbstractThe lithium alkoxides [1‐LiOCR1R2‐2‐NMe2C6H4]2 [R1 = R2 = Ph (1), Cy (2)] react with BCl3 or BF3(Et2O) to give 1‐X2BOCR1R2‐2‐NMe2C6H4 [R1 = R2 = Ph, X = Cl (4); R1 = R2 = Cy, X = Cl (5); R1 = R2 = Ph, X = F (6); R1 = R2 = Cy, X = F (7)]. The lithium amide [1‐LiN(Ph)C(H)Ph‐2‐NMe2C6H4]2 (3) reacts with BCl3 to give 1‐Cl2BN(Ph)C(H)Ph‐2‐NMe2C6H4 (8). Compounds 4 ‐ 8 were characterized spectroscopically (NMR, IR, MS), and crystal structures were determined for 3 ‐ 6.

  DOI：

  10.1002/zaac.200400375