[Ni(η(5)-C4Me4P)(μ-η(1)-C4Me4P)]2 | 186492-54-6

• 英文名称: [Ni(η(5)-C4Me4P)(μ-η(1)-C4Me4P)]2
• CAS: 186492-54-6
• 化学式: C₃₂H₄₈Ni₂P₄
• 分子量: 674.008
• InChiKey: GAXCKJKZTHWMJP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  dichlorobis(η-tetramethylphospholyl)uranium(IV) 、 [Ni(η(5)-C4Me4P)(μ-η(1)-C4Me4P)]2 在 Na/Hg 作用下， 以 四氢呋喃 为溶剂， 以20%的产率得到[Ni2(μ-η(1)-C4Me4P)2][(μ-η(5),η(1)-C4Me4P)2UCl2]2 * 3 THF
  参考文献：
  名称：

  Phospholyl compounds of nickel and uranium

  摘要：

  The phospholyl nickel compound [{Ni(eta(5)-C(4)Me(4)P)(mu-eta(1)-C(4)Me(4)P)}(2)] 1 was prepared by treating NiCl2 with two equivalents of KC(4)Me(4)P in pyridine, whereas reaction of NiCl2 with two equivalents of [U(eta(5)-C(4)Me(4)P)(3)Cl] or an excess of [U(eta(5)-C(4)Me(4)P)(2)Cl-2] afforded the trinuclear complex [Ni{(mu-eta(5),eta(1)-C(4)Me(4)P)(2)UCl2}(2)] 2. Reduction of a 1:2 mixture of 1 and [U(eta(5)-C(4)Me(4)P)(2)Cl-2] by sodium amalgam in tetrahydrofuran gave the tetranuclear compound [{Ni-2(mu-eta(1)-C(4)Me(4)P)(2)}{(mu-eta(5),eta(1)-C(4)Me(4)P)(2)UCl2}(2) . 3C(4)H(8)O] 3. The crystal structures of 1, 2 and 3 have been determined.

  DOI：

  10.1016/s0022-328x(96)06447-9
• 作为产物：
  描述：

  potassium 2,3,4,5-tetramethylphospholide 、 nickel dichloride 以 吡啶 为溶剂， 以92%的产率得到[Ni(η(5)-C4Me4P)(μ-η(1)-C4Me4P)]2
  参考文献：
  名称：

  Phospholyl compounds of nickel and uranium

  摘要：

  The phospholyl nickel compound [{Ni(eta(5)-C(4)Me(4)P)(mu-eta(1)-C(4)Me(4)P)}(2)] 1 was prepared by treating NiCl2 with two equivalents of KC(4)Me(4)P in pyridine, whereas reaction of NiCl2 with two equivalents of [U(eta(5)-C(4)Me(4)P)(3)Cl] or an excess of [U(eta(5)-C(4)Me(4)P)(2)Cl-2] afforded the trinuclear complex [Ni{(mu-eta(5),eta(1)-C(4)Me(4)P)(2)UCl2}(2)] 2. Reduction of a 1:2 mixture of 1 and [U(eta(5)-C(4)Me(4)P)(2)Cl-2] by sodium amalgam in tetrahydrofuran gave the tetranuclear compound [{Ni-2(mu-eta(1)-C(4)Me(4)P)(2)}{(mu-eta(5),eta(1)-C(4)Me(4)P)(2)UCl2}(2) . 3C(4)H(8)O] 3. The crystal structures of 1, 2 and 3 have been determined.

  DOI：

  10.1016/s0022-328x(96)06447-9